Thermodynamic properties of 1-alkyl-3-methylimidazolium bromide ionic liquids; J. Chem. Thermodynamics 39 (2007) 158–166; Y.U. Paulechka; G.J. Kabo; A.V. Blokhin; A.S. Shaplov; E.I. Lozinskaya; Ya.S.

  • 更新时间: 2014-09-14 11:35:14
  • 文献题名: Thermodynamic properties of 1-alkyl-3-methylimidazolium bromide ionic liquids
  • 前三作者: Y.U. Paulechka; G.J. Kabo; A.V. Blokhin; A.S. Shaplov; E.I. Lozinskaya; Ya.S. Vygodskii
  • 文献摘要:
  • 关键词:
  • 所在版面: J. Chem. Thermodynamics 39 (2007) 158–166
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Abstracts
Heat capacities and enthalpies of phase transitions for a series of 1-alkyl-3-methylimidazolium bromide ionic liquids have been measured by adiabatic calorimetry. Thermodynamic properties of the compounds were calculated in the temperature range of (5 to 370) K. Water was found to have an additive contribution to the heat capacities of [C4mim]Br in the liquid state above Tfus and in the solid state below 160 K at w(H2O) < 5*10-3.
Keywords Ionic liquids; Thermodynamic properties; 1-Alkyl-3-methylimidazolium bromides; Synthesis of high-purity ionic liquids
ILs编号 ILs名称
1 1-Ethyl-3-methylimidazolium bromide [C2mim]Br
2 1-Propyl-3-methylimidazolium bromide [C3mim]Br
3 1-Butyl-3-methylimidazolium bromide [C4mim]Br
ILs编号

ρ

~

Vm

μ

~

η

 

γ

κ

λ

Cp

~

Cp,w

DT

Hfm

Hvm

Hm

Sm

n

α

u

ET

 

Tm

Tf

Tc

Td

Tg

1                                          
2                                          
3                                          

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